Eu acho que você está procurando pelo argumento -o:
-o format:
user-defined format. format is a single argument in the form of a blank-separated or comma-separated list, which offers a way to specify individual output columns. The recognized keywords are described in the STANDARD FORMAT SPECIFIERS section below. Headers may be renamed (ps -o pid,ruser=RealUser -o comm=Command) as desired. If all column headers are empty (ps -o pid= -o comm=) then the header line will not be output. Column width will increase as needed for wide headers; this may be used to widen up columns such as WCHAN (ps -o pid,wchan=WIDE-WCHAN-COLUMN -o comm). Explicit width control (ps opid,wchan:42,cmd) is offered too. The behavior of ps -o pid=X,comm=Y varies with personality; output may be one column named "X,comm=Y" or two columns named "X" and "Y". Use multiple -o options when in doubt. Use the PS_FORMAT environment variable to specify a default as desired; DefSysV and DefBSD are macros that may be used to choose the default UNIX or BSD columns.
Então o comando que você quer seria (Ubuntu):
ps -o uid,pid,cmd -ef|grep python
no OpenSolaris o comando é:
ps -o ruser,pid,comm -ef|grep python