Adicione a seguinte linha a ~/.tmux.conf
set -g terminal-overrides "xterm*:kLFT5=\eOD:kRIT5=\eOC:kUP5=\eOA:kDN5=\eOB:smkx@:rmkx@"
Fonte: link
Ctrl and arrow keys doesn't work in putty! What do I do?
putty inverts the sense of the cursor key mode on ctrl, which is a bit hard for tmux to detect properly. To get ctrl keys right, change the terminfo settings so kUP5 (Ctrl-Up etc) are the adjusted versions, and disable smkx/rmkx so tmux doesn't change the mode. For example with this line in .tmux.conf (assuming you have TERM set to xterm):
set -g terminal-overrides "xterm*:kLFT5=\eOD:kRIT5=\eOC:kUP5=\eOA:kDN5=\eOB:smkx@:rmkx@"
Note that this will only work in tmux 1.2 and above.