Isso funcionou.
rpm -Uvh http://yum.postgresql.org/9.3/redhat/rhel-6-x86_64/pgdg-centos93-9.3-1.noarch.rpm
yum install postgresql93-server postgresql93-contrib
service postgresql-9.3 initdb
/etc/init.d/postgresql-9.3 start
chkconfig postgresql-9.3 on
Isso também pode funcionar:
yum install pgdg-centos93.noarch # in place of rpm
service postgres-9.3 start # in place of init.d