O Windows 10 fornece uma nova função para atingir seu objetivo. É chamado de "VPN acionada por aplicativos" e "Filtros de tráfego".
App-triggered VPN
VPN profiles in Windows 10 can be configured to connect automatically on the launch of a specified set of applications. This feature was included in Windows 8.1 as "On demand VPN". The applications can be defined using the following: •Package family name for Universal Windows Platform (UWP) apps •File path for Classic Windows applications
Para informações detalhadas, leia este link .