Você está tentando redirecionar o e-mail para o gmail, mas sua configuração não aceita a retransmissão de e-mails para o gmail para que ele retorne 554 códigos de rejeição.
em postconf
relay_domains_reject_code (default: 554) The numerical Postfix SMTP
server response code when a client request is rejected by the
reject_unauth_destination recipient restriction.
para corrigir o valor correto do problema de retransmissão do parâmetro mydestination de acordo com postconf
relay_domains (default: $mydestination) What destination domains (and
subdomains thereof) this system will relay mail to. For details about
how the relay_domains value is used, see the description of the
permit_auth_destination and reject_unauth_destination SMTP recipient
restrictions.
Domains that match $relay_domains are delivered with the
$relay_transport mail delivery transport. The SMTP server validates
recipient addresses with $relay_recipient_maps and rejects
non-existent recipients. See also the relay domains address class in
the ADDRESS_CLASS_README file.
Note: Postfix will not automatically forward mail for domains that
list this system as their primary or backup MX host. See the
permit_mx_backup restriction in the postconf(5) manual page.
Specify a list of host or domain names, "/file/name" patterns or
"type:table" lookup tables, separated by commas and/or whitespace.
Continue long lines by starting the next line with whitespace. A
"/file/name" pattern is replaced by its contents; a "type:table"
lookup table is matched when a (parent) domain appears as lookup key.
Specify "!pattern" to exclude a domain from the list. The form
"!/file/name" is supported only in Postfix version 2.4 and later.
Pattern matching of domain names is controlled by the presence or
absence of "relay_domains" in the parent_domain_matches_subdomains
parameter value.