A opção / 3GB não se aplica a edições de 64 bits do Windows
Applications that are compiled with the /LARGEADDRESSAWARE option, as would be required to take advantage of the /3GB switch in 32-bit Windows, will automatically be able to address 4 GB of virtual memory without any boot time switches or changes to x64 Windows. Plus, of course, the operating system does not have to share that 4 GB of space. Therefore, it is not constrained at all
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A pool of system Page Table Entries (PTEs) that is used to map system pages such as I/O space, Kernel stacks, and memory descriptor lists. 64-bit programs use a 16-terabyte tuning model (8 terabytes User and 8 terabytes Kernel). 32-bit programs still use the 4-GB tuning model (2 GB User and 2 GB Kernel). This means that 32-bit processes that run on 64-bit versions of Windows run in a 4-GB tuning model (2 GB User and 2GB Kernel). 64-bit versions of Windows do not support the use of the /3GB switch in the boot options. Theoretically, a 64-bit pointer could address up to 16 exabytes. 64-bit versions of Windows have currently implemented up to 16 terabytes of address space