Isso é algo que pode acontecer quando você tem smtp_use_tls = yes
.
smtp_use_tls
(default:no
)Opportunistic mode: use TLS when a remote SMTP server announces STARTTLS support, otherwise send the mail in the clear. Beware: some SMTP servers offer STARTTLS even if it is not configured. With Postfix < 2.3, if the TLS handshake fails, and no other server is available, delivery is deferred and mail stays in the queue. If this is a concern for you, use the smtp_tls_per_site feature instead.