Você precisa de sys-boot/os-prober
para detectar janelas. Na página wiki do Gentoo do Grub2:
Additional software
Optionally, install the os-prober utility (provided through the sys-boot/os-prober package) to have GRUB2 probe for other operating systems when running the grub-mkconfig command. In most instances, this will enable GRUB2 to automatically detect other operating systems including Windows 7, 8.1, 10, other distributions of Linux, etc. root
emerge --ask --newuse sys-boot/os-prober
The GRUB2 (and optionally sys-boot/os-prober) installations do not automatically enable the boot loader. These only install the software on the operating system, but to install the boot loader to the system itself (so that it is used when booting the system), additional steps need to be taken, which are covered in the Configuration section.
E:
os-prober and UEFI in chroot
The sys-boot/os-prober utility is used to discover alternate installs, such as Microsoft Windows. To function properly, it needs to have access to information from the live environment's udev to test for the EFI System Partition.
Run these commands in the host environment to provide the required files (example shows Gentoo mounted on /mnt/gentoo like in the Handbook):
root #mkdir -p /mnt/gentoo/run/udev root #mount -o bind /run/udev /mnt/gentoo/run/udev root #mount --make-rslave /mnt/gentoo/run/udev'