Após comentários do Ramhound, criei um script e adicionei-o ao início automático.
@echo off ECHO Waiting a while for a network connection... timeout /t 7 ping -n 1 -w 25 hostReachableFromOfficeOnly | find "Reply" > nul if errorlevel 1 goto :HOME goto :OFFICE :OFFICE ECHO Office start /d"%ProgramFiles(x86)%\Microsoft Lync" communicator.exe start /d"%ProgramFiles(x86)%\Atlassian\SourceTree\" SourceTree.exe start /d"C:\work\IDE\eclipse-jee-juno-SR2-win32-x86_64\" eclipse.exe start /d"%ProgramFiles(x86)%\Microsoft\ Office\Office14" OUTLOOK.EXE goto :END :HOME ECHO Home! :END
Obrigado por todas as respostas.