O primeiro define o limite de conexão que você deseja para conexões HTTP 1.0, e o segundo é para conexões HTTP 1.1.
De Wikipedia :
HTTP/1.1 is a revision of the original HTTP (HTTP/1.0). In HTTP/1.0 a separate connection to the same server is made for every resource request. HTTP/1.1 can reuse a connection multiple times to download images, scripts, stylesheets et cetera after the page has been delivered. HTTP/1.1 communications therefore experience less latency as the establishment of TCP connections presents considerable overhead.