No guia de administração do ZFS:
"Os dispositivos podem ser fatias individuais em um disco pré-formatado ou podem ser discos inteiros que o ZFS formata como uma única fatia grande."
Então, sim, você poderia criar duas partições de 1 TB nessas unidades de 2 TB, usá-las para o RAID-Z vdev e o espaço restante para armazenamento não redundante.
No entanto, de acordo com o Guia de práticas recomendadas do ZFS, você pode apresentar um desempenho inferior:
For production systems, use whole disks rather than slices for storage
pools for the following reasons:
Allows ZFS to enable the disk's write cache for those disks that have write caches. If you are using a RAID array with a non-volatile
write cache, then this is less of an issue and slices as vdevs should
still gain the benefit of the array's write cache.
For JBOD attached storage, having an enabled disk cache, allows some synchronous writes to be issued as multiple disk writes followed by a
single cache flush allowing the disk controller to optimize I/O
scheduling. Separately, for systems that lacks proper support for SATA
NCQ or SCSI TCQ, having an enabled write cache allows the host to
issue single I/O operation asynchronously from physical I/O.
The recovery process of replacing a failed disk is more complex when disks contain both ZFS and UFS file systems on slices.