No Windows, você pode definir o local de pesquisa no registro.
Por meio do arquivo de configuração do PHP :
- As of PHP 5.2.0, the location of the php.ini file can be set for different versions of PHP. The following registry keys are examined in order: [HKEY_LOCAL_MACHINE\SOFTWARE\PHP\x.y.z], [HKEY_LOCAL_MACHINE\SOFTWARE\PHP\x.y] and [HKEY_LOCAL_MACHINE\SOFTWARE\PHP\x], where x, y and z mean the PHP major, minor and release versions. If there is a value for IniFilePath in any of these keys, the first one found will be used as the location of the php.ini (Windows only).
- [HKEY_LOCAL_MACHINE\SOFTWARE\PHP], value of IniFilePath (Windows only).