Desculpe, não há solução para isso. O postfix é muito compatível com RFC e insiste em receber uma resposta correta.
Existem métodos para reescrever a resposta para algo completamente diferente, mas para isso a resposta tem que realmente ocorrer. No seu caso, não há resposta (aos olhos do Postfix e RFC 5321) e assim ocorre um tempo limite.
Apenas para completar o excerto da seção 2.3.0 da RFC 5321:
Lines consist of zero or more data characters terminated by the
sequence ASCII character "CR" (hex value 0D) followed immediately by
ASCII character "LF" (hex value 0A). This termination sequence is
denoted as <CRLF> in this document. Conforming implementations MUST
NOT recognize or generate any other character or character sequence
as a line terminator. Limits MAY be imposed on line lengths by
servers (see Section 4).
In addition, the appearance of "bare" "CR" or "LF" characters in text
(i.e., either without the other) has a long history of causing
problems in mail implementations and applications that use the mail
system as a tool. SMTP client implementations MUST NOT transmit
these characters except when they are intended as line terminators
and then MUST, as indicated above, transmit them only as a <CRLF>
sequence.