Você pode chamar o script em /etc/rc.local
, que é o local correto para os scripts personalizados serem executados na inicialização.
#!/bin/sh -e
#
# rc.local
#
# This script is executed at the end of each multiuser runlevel.
# Make sure that the script will "exit 0" on success or any other
# value on error.
#
# In order to enable or disable this script just change the execution
# bits.
#
# By default this script does nothing.
/usr/local/bin/your-script
exit 0