verifique isso
$awk -F"[>|<]" '{print $5,$9}' input.txt
5 Ukraine
3 Vietnam
3 Taiwan
3 Netherlands
3 South Korea
3 Great Britain
usando sed commnad
$ sed "s#<TR><TD>\(.\)</TD><TD>\(.*\)</TD></TR># #" input.txt
5 Ukraine
3 Vietnam
3 Taiwan
3 Netherlands
3 South Korea
3 Great Britain