Isso funcionou até recentemente.
yum -y install wget gmp-devel rpm-devel mpfr-devel rpm
wget -O /etc/yum.repos.d/slc6-devtoolset.repo http://linuxsoft.cern.ch/cern/devtoolset/slc6-devtoolset.repo
rpm --import http://linuxsoft.cern.ch/cern/slc6X/x86_64/RPM-GPG-KEY-cern
yum install -y devtoolset-1.1
Os erros são:
Error: Package: devtoolset-1.1-gcc-c++-4.7.2-5.el6.x86_64 (slc6-devtoolset)
Requires: libgmp.so.3()(64bit)
Error: Package: devtoolset-1.1-gcc-gfortran-4.7.2-5.el6.x86_64 (slc6-devtoolset)
Requires: libgmp.so.3()(64bit)
Error: Package: devtoolset-1.1-systemtap-client-1.8-8.el6.x86_64 (slc6-devtoolset)
Requires: librpmio.so.1()(64bit)
Error: Package: devtoolset-1.1-gcc-4.7.2-5.el6.x86_64 (slc6-devtoolset)
Requires: libmpfr.so.1()(64bit)
Error: Package: devtoolset-1.1-gcc-4.7.2-5.el6.x86_64 (slc6-devtoolset)
Requires: libgmp.so.3()(64bit)
Error: Package: devtoolset-1.1-gdb-7.5.0.20120926-26.el6.x86_64 (slc6-devtoolset)
Requires: libpython2.6.so.1.0()(64bit)
Error: Package: devtoolset-1.1-systemtap-client-1.8-8.el6.x86_64 (slc6-devtoolset)
Requires: librpm.so.1()(64bit)
Error: Package: devtoolset-1.1-systemtap-devel-1.8-8.el6.x86_64 (slc6-devtoolset)
Requires: librpmio.so.1()(64bit)
Error: Package: devtoolset-1.1-gcc-c++-4.7.2-5.el6.x86_64 (slc6-devtoolset)
Requires: libmpfr.so.1()(64bit)
Error: Package: devtoolset-1.1-systemtap-devel-1.8-8.el6.x86_64 (slc6-devtoolset)
Requires: librpm.so.1()(64bit)
Error: Package: devtoolset-1.1-gcc-gfortran-4.7.2-5.el6.x86_64 (slc6-devtoolset)
Requires: libmpfr.so.1()(64bit)
Todas essas coisas, como libgmp, estão instaladas. As versões não são as mesmas, no entanto.